Name
|
|
EINECS
|
252-681-0
|
CAS No.
|
35691-65-7
|
Density
|
1.889 g/cm3
|
PSA
|
47.58000
|
LogP
|
2.34236
|
Solubility
|
insoluble in water
|
Melting Point
|
48-50 °C
|
Formula
|
C6H6Br2N2
|
Boiling Point
|
338.6 °C at 760 mmHg
|
Molecular Weight
|
265.935
|
Flash Point
|
158.6 °C
|
Transport Information
|
UN 3439
|
Appearance
|
Crystals with a pungent odor
|
Safety
|
26-36/37/39-45
|
Risk Codes
|
20/22-37/38-41-34-22
|
Molecular Structure
|
|
Hazard Symbols
|
Xn
|
Synonyms
|
1,2-Dibromo-2,4-dicyanobutane;1-Bromo-1-(bromomethyl)-1,3-propanedicarbonitrile;2-Bromo-2-(bromomethyl)glutaronitrile;BBMG;Bromothalonil;DBDCB;MDBGN;Merguard 1105;Methyldibromoglutaronitrile;Tektamer;Tektamer 38;Tektamer38AD;Tuopai DM 01;
|
|
|
1,2-DIBROMO-2,4-DICYANOBUTANE Synthetic route
ConditionsConditions | Yield |
---|
With bromine Irradiation; | |
ConditionsConditions | Yield |
---|
Stage #1: acrylonitrile With triethylamine; zinc(II) chloride for 1h; Autoclave; Green chemistry; Large scale; Stage #2: With bromine In water at 50 - 100℃; for 2h; Green chemistry; Large scale; | 510 kg |
ConditionsConditions | Yield |
---|
In acetonitrile Product distribution; Mechanism; other solvents; | |
1,2-DIBROMO-2,4-DICYANOBUTANE Chemical Properties
1,2-DIBROMO-2,4-DICYANOBUTANE(35691-65-7) is the chemical compound with the formula C
6H
6Br
2N
2.Its molar weight is 265.93g/mol.
1,2-DIBROMO-2,4-DICYANOBUTANE(35691-65-7) is also named 2-bromo-2-(bromomethyl)-glutaronitril;2-bromo-2-(bromomethyl)-pentanedinitril; methyldibromoglutaronitrile;tektamer38;dbdcb;2-bromo-(2-bromomethyl)glutaronitrile;2-Bromo-2-(bromomethyl)pentanedinitrile.
Melting point: 48-50
oC
Flash Point: 158.6
oC
Boiling Point: 338.6
oC at 760 mmHg
Storage temp.: 2-8
oC
Index of Refraction: 1.553
Molar Refractivity: 45.1 cm
3 Molar Volume: 140.7 cm
3 Surface Tension: 57 dyne/cm
Density: 1.889 g/cm
3 Enthalpy of Vaporization: 58.2 kJ/mol
Vapour Pressure: 9.71E-05 mmHg at 25
oC
The chemical structure of 1,2-DIBROMO-2,4-DICYANOBUTANE(35691-65-7) is
.
1,2-DIBROMO-2,4-DICYANOBUTANE Uses
1,2-DIBROMO-2,4-DICYANOBUTANE(35691-65-7) is used as preservative for latex paints, adhesives, latex emulsions, dispersed pigments, joint cements, metal working fluids.
1,2-DIBROMO-2,4-DICYANOBUTANE Consensus Reports
Reported in EPA TSCA Inventory.
1,2-DIBROMO-2,4-DICYANOBUTANE Safety Profile
Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NO
x and Br
−.
Hazard Codes:
Xn
Risk Statements: 20/22-37/38-41-34-22
20/22: Harmful by inhalation and if swallowed
37/38: Irritating to respiratory system and skin
41: Risk of serious damage to eyes
34: Causes burns
22: Harmful if swallowed
Safety Statements: 26-36/37/39-45
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR: 3439
RTECS: MA5599000
HazardClass: 9
PackingGroup: III
Hazardous Substances Data: 35691-65-7(Hazardous Substances Data) .
1,2-DIBROMO-2,4-DICYANOBUTANE Specification
It should be kept in a cool, dry, dark location in a tightly sealed container or cylinder,and keep away from incompatible materials, ignition sources and untrained individuals.stored in secure and label area.,and protect containers/cylinders from physical damage.